What UCI HAR teaches you
In the UCI HAR dataset, thirty people walked, went up and down stairs, and sat, stood and lay down with a phone on their belt. The first models built on the 561 features made very few mistakes on the activities with movement. Almost all the errors were between sitting and standing.
That's the lesson of the mix-up table. One precise weak spot explains almost all the error. To tell sitting from standing with a phone on the belt, you don't need a bigger model. You need one more piece of information, for example the angle of the thigh, which you can't measure from the belt.